Prodotti della ricerca

 
Titolo: Characterization of boron doped diamond electrodes during oxidation processes: relationship between electrochemical activity and ageing time
Autori: 
Data di pubblicazione: 2006
Rivista: 
THIN SOLID FILMS  
Abstract: The paper presents the results on the evolution of electronic features and electrochemical activity of boron doped diamond samples during oxidative ageing tests. For 1 cm(2) of electrode surface, the resistance increases from 7 12 to about 200 12 during the first hour of work, than it decreases down to 2 Omega in 350 h. In this condition, high values of heterogeneous electron-transfer rate constants for ferro/ferricyanide are measured in the order of 10(-4) cm/s, indicating a semi-metallic behaviour of the samples. Results from Raman analyses are also presented and a possible explanation of the observed behaviour of the samples is proposed, in terms of both the intrinsic movement of the H within the structure of the film and the variation of free acceptor levels associated to the B atoms in the lattice. (c) 2006 Elsevier B.V. All rights reserved.
Handle: http://hdl.handle.net/11584/106852
Tipologia:1.1 Articolo in rivista

File in questo prodotto:
Non ci sono file associati a questo prodotto.
credits unica.it | accessibilità Università degli Studi di Cagliari
C.F.: 80019600925 - P.I.: 00443370929
note legali | privacy

Nascondi la toolbar