Prodotti della ricerca
Titolo: | Lithium 2,3-dihydro-1-benzothiophene-1,1-dioxide: synthesis, characterization, DFT calculations and reactivity towards aldehydes and azometines |
Autori: | |
Data di pubblicazione: | 2007 |
Rivista: | |
Abstract: | The sulfonyl carbanion derived from 2,3-dihydro-1-benzothiophene-1,1-dioxide and its lithium salt has been investigated by DFT calculations. NMR and IR spectroscopic analyses showed that the lithium sulfonyl carbanion exists in solution as a monomer in equilibrium with a dimer. The lithium carbanion was treated with aldehydes and azomethynes to give chiral hydroxy and amino derivatives. The stereochemistry of the products and the diastereoselectivity of the reaction were investigated |
Handle: | http://hdl.handle.net/11584/109901 |
Tipologia: | 1.1 Articolo in rivista |
File in questo prodotto:
Non ci sono file associati a questo prodotto.