|Titolo:||Evaluation of the alpha-phenylvinyl cation as a chemical ionization reagent for the differentiation of isomeric substituted phenols in an ITMS|
|Data di pubblicazione:||2015|
|Abstract:||Ion–molecule reactions between the α-phenylvinyl cation and isomeric naturally occurring phenols were investigated using a quadruple ion trap mass spectrometer. The α-phenylvinyl cation m/z 103, generated by chemical ionization from phenylacetylene, reacts with neutral aromatic compounds to form the characteristic species: [M+ 103]+ adduct ions and the trans-vinylating product ions [M+ 25]+, which correspond to [M+ 103]+ adduct after the loss of benzene. Isomeric differentiation of several ring-substituted phenols was achieved by using collision-induced dissociation of the [M + 103]+ adduct ions. This method also showed to be effective in the differentiation of 4-ethylguaiacol from one of its structural isomers that displays identical EI and EI/MS/MS spectra. The effects of gas-phase alkylation with phenylvinyl cation on the dissociation behavior were examined using mass spectrometryn and labeled derivatives.|
|Tipologia:||1.1 Articolo in rivista|
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