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Titolo: Redox Switchable Chromophores based on Metal (Ni, Pd, Pt) Mixed-Ligand Dithiolene Complexes Showing Molecular Second-order NLO Activity
Autori: 
Data di pubblicazione: 2011
Rivista: 
INORGANIC CHEMISTRY  
Abstract: The synthesis and full characterization of the redox-active nickel triad mixed-ligand dithiolene complexes based on Bz2pipdt = 1,4-dibenzylpiperazine-3,2-dithione and dmit = 2-thioxo-1,3-dithiole-4,5-dithiolate ligands are reported. These complexes show a reversibly bleacheable solvatochromic peak and a remarkably high negative molecular first hyperpolarizability, whose values depend on the metal being highest for the platinum(II) compound
Handle: http://hdl.handle.net/11584/108835
Tipologia:1.1 Articolo in rivista

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