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Titolo: Synthesis of tertiary cyclobutanols through stereoselective ring expansion of oxaspiropentanes induced by Grignard reagents
Autori: 
Data di pubblicazione: 2000
Rivista: 
TETRAHEDRON  
Abstract: The stereoselectivity of the ring expansion of oxaspiropentanes to cyclobutanols induced by Grignard reagents has been studied. It has been found that the reaction occurs through the intermediacy of a cyclobutanone, formed stereospecifically, whereas the attack of the Grignard reagent on the carbonyl group of the cyclobutanone is stereospecific only in the case of the oxaspiropentanes derived from aldehydes.
Handle: http://hdl.handle.net/11584/6491
Tipologia:1.1 Articolo in rivista

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