Prodotti della ricerca
Titolo: | Structure of the c(2x2)-Br/Pt(110) surface |
Autori: | |
Data di pubblicazione: | 2002 |
Rivista: | |
Abstract: | We present a detailed investigation of the c(2x2)-Br/Pt(110) adlayer structure supplemented by the analysis of the (1x2) missing-row (MR) structure of the clean Pt(110) surface. Quantitative low energy electron diffraction analyses and first-principles calculations are in impressive agreement in both cases. The clean surface reconstruction is determined with unprecedented accuracy. For the adsorbate, the analysis retrieves a simple Br-adlayer structure with the Br atoms residing in every second short bridge position on the close-packed Pt rows with the MR reconstruction lifted. The Br-Pt bond length L=2.47 Angstrom is almost equal to the sum of the atomic radii. The substrate below the adsorbate exhibits a contraction of the first layer spacing which amounts to half of that calculated for an unreconstructed clean surface. |
Handle: | http://hdl.handle.net/11584/63993 |
Tipologia: | 1.1 Articolo in rivista |
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