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Titolo: Stereospecific palladium(0)-catalyzed reduction of 2-cyclobutylidenepropyl esters. A versatile preparation of diastereoisomeric monoterpenoids: (±)- Fragranol and (±)- Grandisol
Autori: 
Data di pubblicazione: 2003
Rivista: 
TETRAHEDRON  
Abstract: Mixtures of (E and Z)-2-cyclobutylidenepropyl sulfonates, readily available from α,α-disubstituted cyclobutanones arising from suitable cyclopropane derivatives ring expansion, underwent regioselective and stereospecific reduction by formate anion to offer, through π-1,1- trimethyleneallylpalladium complexes formed upon treatment with palladium(0), a new and convenient entry to the diastereomeric four-membered ring monoterpenoids (±)-fragranol and (±)-grandisol.
Handle: http://hdl.handle.net/11584/109814
Tipologia:1.1 Articolo in rivista

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