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Titolo: From (phenylsulfanyl)cycloalkanecarbaldehydes to optically active spirocyclic tetrahydrofurans: stereospecific resolution of symmetric aldehydes through (S)-proline-catalysed aldol reaction
Autori: 
Data di pubblicazione: 2014
Rivista: 
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY  
Abstract: A variety of enantiomerically enriched tetrahydrofuran spirocyclic derivatives have been synthesised by a sequential enantioselective proline-induced stereospecific resolution through aldol reaction of (E/Z)-(phenylsulfanyl)cycloalkane-carbaldehydes followed by a ketone reduction, acid-catalysed [1,2]-SPh stereospecific migration, and ring-closure reaction.
Handle: http://hdl.handle.net/11584/109801
Tipologia:1.1 Articolo in rivista

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